Hexafluoropropylene oligomers, also known as perfluoroolefin oligomers, are mixed oligomers prepared from hexafluoropropylene, mainly including hexafluoropropylene dimer (HFPD) and hexafluoropropylene trimer (HFPT).
From the perspective of upstream raw materials, hexafluoropropylene (HFP), also known as perfluoropropylene, is an organic compound, and its preparation methods include the thermal decomposition of difluorochloromethane and the thermal decomposition of tetrafluoroethylene. Hexafluoropropylene has a wide range of applications and the market demand is growing. In 2023, the market demand in China will reach about 70,000 tons.
Hexafluoropropylene dimer (HFPD) is a compound obtained by oligomerization of two hexafluoropropylene molecules under the action of a catalyst. Due to the presence of carbon-fluorine bonds in its molecular structure, hexafluoropropylene dimer has the characteristics of strong heat resistance, high chemical stability, water-repellent, oil-repellent, and antifouling. Based on this, hexafluoropropylene dimer can be used to make fluorinated surfactants (such as wetting agents, emulsifiers, penetrants), fluorinated cleaning agents, etc.
Hexafluoropropylene trimer (HFPT), also known as perfluorononene, is obtained by trimerization of hexafluoropropylene gas. Hexafluoropropylene trimer has three isomers, namely perfluoro-2,4-dimethyl-3-heptene (T-1), perfluoro-4-methyl-3-isopropyl-2-pentene (T-2), and perfluoro-2,4-dimethyl-3-ethyl-2-pentene (T-3). Hexafluoropropylene trimer is an environmentally friendly solvent and can be used as a desiccant, cleaning agent, diluent, etc.

Hexafluoropropylene trimer (HFP Trimer) is an important fluorine-containing fine chemical, widely used in electronics, medicine, coatings and high-performance materials. With the rapid development of China's economy and technological progress, the demand for hexafluoropropylene trimer has increased year by year, and the market size has continued to expand.
Since 2010, China's hexafluoropropylene trimer industry has experienced a rapid development stage. In 2010, the market size of hexafluoropropylene trimer in China was only RMB 250 million, and the output was about 1,500 tons. With the expansion of downstream application fields and the improvement of technical level, market demand has gradually increased. In 2015, the market size grew to RMB 680 million and the output reached 4,000 tons. Entering 2020, despite the impact of the global COVID-19 pandemic, China's hexafluoropropylene trimer industry has maintained a steady growth trend. In 2020, the market size reached RMB 1.23 billion and the output was 7,500 tons. This growth is mainly due to the strong demand in the electronics industry and high-performance materials market, especially the development of new energy vehicles and 5G communication technology, which further promoted the application of hexafluoropropylene trimer.
In 2024 , the market size of China's hexafluoropropylene trimer industry further expanded to RMB 1.85 billion, and the output exceeded 10,000 tons. This growth was mainly due to the following aspects:

With the rapid development of high-tech industries such as new energy vehicles, 5G communications, and semiconductor manufacturing, the demand for hexafluoropropylene trimer continues to increase.
Domestic enterprises have made remarkable progress in production processes and technology research and development, improving product quality and production efficiency.
The Chinese government has introduced a series of support policies to encourage the development of new materials and high-end manufacturing industries, providing a good external environment for the hexafluoropropylene trimer industry.
It is estimated that by 2025, the market size of China's hexafluoropropylene trimer industry will reach RMB 2.68 billion, and the output is expected to reach 14,000 tons. This forecast is based on the following considerations:
With the further development of new energy vehicles, 5G communications, semiconductor manufacturing and other fields, the demand for hexafluoropropylene trimer will continue to increase.
Domestic companies will continue to increase investment in research and development, improve product quality and production efficiency, and enhance market competitiveness.
The government will continue to introduce relevant policies to support the development of new materials and high-end manufacturing industries and provide strong policy guarantees for the hexafluoropropylene trimer industry.
China's hexafluoropropylene trimer (HFP) industry has developed rapidly in recent years, and the market size continues to expand.
In 2018, the total output of China's HFP market reached about 15,000 tons, an increase of 8% year-on-year. This growth was mainly due to the rapid development of downstream application fields, especially the increase in demand in the fields of electronic chemicals, pharmaceutical intermediates and high-performance materials.
Electronic chemicals : With the rapid development of industries such as 5G communications, semiconductors and new energy vehicles, the demand for electronic chemicals has increased significantly. In 2023, the demand for HFP in the electronic chemicals field will reach 40%, and it is expected to further increase to 45% by 2025.
Pharmaceutical intermediates : HFP is also increasingly used in pharmaceutical intermediates, especially in the research and development of new drugs. In 2023, the demand for HFP in the pharmaceutical intermediates field will account for about 25%, and it is expected to reach 30% by 2025.
High-performance materials : The application of HFP in high-performance materials, such as specialty rubbers and coatings, is also showing good growth. In 2023, the demand for HFP in the high-performance materials field will account for about 35%, and it is expected to reach 37% by 2025.
Hexafluoropropylene is mainly used to synthesize fluoropolymers, such as fluororubber and fluororesin, which have excellent performance in high temperature and chemical corrosion environments. With the continuous expansion of downstream markets , the market demand for hexafluoropropylene is also showing a steady growth trend.
Hexafluoropropylene is one of the important fluorine-containing polymer materials, with a wide range of downstream applications and a growing market demand. In recent years, China's hexafluoropropylene production capacity and output have expanded significantly. In recent years, the global and Chinese hexafluoropropylene market has continued to expand. The hexafluoropropylene report shows that China's hexafluoropropylene production will be about 83,000 tons in 2022. With the continuous advancement and innovation of production technology, the production efficiency and product quality of hexafluoropropylene will continue to improve. This will help reduce production costs and improve market competitiveness.
There are many hexafluoropropylene manufacturers and the market competition is fierce. Most of China's hexafluoropropylene manufacturers are large fluorine chemical companies , and Jiayuan follows closely. With the rapid development of downstream industries, China's HFP production capacity and output scale have expanded significantly in recent years. In 2024, China's hexafluoropropylene production will exceed 83,000 tons, and market demand will maintain a growth trend. The global and Chinese hexafluoropropylene market scale continues to expand, and the total effective market production capacity has reached 115,600 tons/year .
the main producers of hexafluoropropylene include DuPont, 3M, and Daikin Industries, Ltd. In China, hexafluoropropylene manufacturers including Jiayuan have a certain production scale and market share. With the improvement and innovation of technology, the production efficiency and product quality of hexafluoropropylene are constantly improving.

Hexafluoropropylene is mainly produced by chemical reactions such as cracking of tetrafluoroethylene (TFE), decarboxylation of perfluorocarboxylic acid or perfluorocarboxylate. Among them, cracking of tetrafluoroethylene is the most important production process. In addition, hexafluoropropylene is produced by direct cracking of R22, thermal decomposition of perfluorocyclobutane and its isomers, etc., but these methods are rarely used in industry.
The reaction process of tetrafluoroethylene cracking to produce hexafluoropropylene is complex and involves multiple side reactions. It requires precise control of reaction conditions and catalysts to improve the yield and purity of hexafluoropropylene. The cracking reaction is carried out under high temperature and high pressure, and has extremely high requirements on equipment materials and sealing performance to prevent reactant leakage and safety accidents. The cracking reaction is an endothermic reaction that consumes a lot of heat energy, and the by-products produced during the reaction also need to be subsequently processed, which increases energy consumption and costs.
The current status analysis of the hexafluoropropylene industry mentioned the development of new high-efficiency catalysts to improve the activity and selectivity of tetrafluoroethylene cracking reactions and reduce the occurrence of side reactions, thereby increasing the yield and purity of hexafluoropropylene. Reaction condition optimization optimizes the cracking reaction process by precisely controlling reaction temperature, pressure, residence time and other conditions, reducing energy consumption and the generation of by-products. Comprehensively utilize the by-products produced by the cracking reaction, such as further processing by-products such as octafluorocyclobutane into other valuable chemicals, to improve resource utilization and economic benefits.
In summary, the production process level of hexafluoropropylene industry is constantly improving, but it still needs further optimization and innovation. Driven by factors such as technological innovation, industrial integration and market demand growth, Jiayuan hexafluoropropylene industry will usher in a broader development prospect.
Dear customers and friends, when you are looking for high-quality hexafluoropropylene products in the dazzling market, we sincerely welcome you to choose our company for ordering. Our company has been deeply involved in the fluorine chemical industry for many years, and has accumulated rich experience and strong strength. It has a professional R&D team to ensure that each product is carefully polished and has excellent quality and outstanding performance. Whether it is product quality, logistics , or after-sales service, we strive to be perfect . During the Spring Festival, considering the particularity of logistics and other aspects, we have comprehensively optimized and adjusted the delivery process. We communicated and coordinated closely with logistics partners in advance and formulated a delivery plan for special periods to ensure that your goods can be delivered safely and in time. Although the delivery during the Spring Festival is different from usual, our pursuit of perfection has never changed. Whether it is product quality control, accurate presentation of functions, or the intimacy of after-sales service, we go all out to achieve perfection.
We always put customer satisfaction first and cherish every choice you make. So, when you need hexafluoropropylene, please do not hesitate and welcome to order from our company. Believe us, we will not let you down during this Spring Festival and will definitely bring you a quality experience beyond your imagination.
3N High-Purity CTFE for Advanced Fluoropolymer Manufacturing
I. High-purity trifluorochloroethylene, serving the needs of fine polymerizationChlorotrifluoroethylene (CTFE) is an important fluorinated polymer monomer with CAS number 79-38-9 and molecular formula C₂ClF₃. CTFE can be used to produce chlorotrifluoroethylene resins and is used in the synthesis of related plastics, elastomers, and high-performance lubricants.Changzhou Jiayuan Chemical Co., Ltd. provides trifluorochloroethylene products with a purity of up to 3N . For manufacturers of high-performance fluorinated materials, the core value of high-purity monomers lies in providing a clearer raw material quality basis for polymerization reactions, reducing the interference of non-target impurities on process evaluation, and supporting product consistency control. II. Special Applications of High-Purity Raw Materials: Development of High-Performance PCTFE MaterialsPolychlorotrifluoroethylene (PCTFE) has good chemical resistance and gas and water vapor barrier properties, and can be used in high-barrier packaging, sealing components, cryogenic equipment and certain industrial materials.During PCTFE polymerization, the composition of impurities in the monomer can affect the polymerization reaction and the final resin quality. US Patent Document US5124494A discusses the byproducts, low-boiling-point impurities, and preparation of high-purity monomers in the PCTFE production process, illustrating that impurity control is a crucial step in obtaining suitable polymerization feedstocks.Therefore, 3N high-purity CTFE is particularly noteworthy for companies requiring stringent raw material acceptance, stable polymerization processes, and high-performance resin development. For applications such as low-temperature sealing and high-barrier materials, verification must be conducted in conjunction with resin grade, processing method, and end-use standards; the final product performance cannot be directly inferred from monomer purity alone. III. 3N Purity and Key Impurity ManagementA total purity of 3N means that, according to the corresponding purity definition, the total amount of non-target components is approximately 0.01%. However, total purity does not indicate the specific content of each impurity. For demanding polymerization applications, the purchaser should also pay attention to moisture, residual monomers, by-products, stabilizers, and other process-related impurities, and verify the testing methods and batch inspection reports.Jiayuan Chemical's trifluorochloroethylene products can achieve a purity of up to 3N. Customers can further confirm product specifications, critical impurity limits, packaging methods, and supply requirements based on their actual polymerization route and material application. ConclusionFor the development of high-performance PCTFE resins and other fluoropolymers, monomer purity and impurity control are crucial aspects of raw material evaluation. Jiayuan Chemical provides trifluorochloroethylene with a purity of up to 3N. Fluoropolymer manufacturers are welcome to inquire about product specifications, testing documents, and supply solutions. FAQ1. What applications are suitable for 3N high-purity trifluorochloroethylene?It can be primarily evaluated for use in the production of PCTFE and related fluoropolymers, and is particularly suitable for polymerization processes that emphasize raw material quality and impurity management. Specific applicability needs to be verified by the customer. 2. Why is it necessary to control impurities in high-purity trifluorochloroethylene?Different impurities can affect the polymerization reaction or the final resin quality. In addition to total purity, the content of critical impurities should be confirmed according to process requirements.
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2026-10-23
Jiayuan Chemical: High-purity hexafluorobutadiene aids in precision etching
As advanced semiconductor manufacturing demands increasingly sophisticated high aspect ratio structures and precise pattern control, the purity and process compatibility of electronic specialty gases are becoming increasingly important. Hexafluorobutadiene (C₄F₆) is a specialty gas used for etching semiconductor dielectrics. Changzhou Jiayuan Chemical Co., Ltd. can provide high-purity hexafluorobutadiene with a purity of up to 99.995%, offering product options for related process applications. I. High-requirement etching processesResearch published by the National Institute of Standards and Technology (NIST) indicates that hexafluorobutadiene is suitable for critical semiconductor etching processes requiring high selectivity and high aspect ratio. Its application value lies in helping process developers optimize etching conditions for different thin film materials and structures; however, the actual effectiveness still needs to be evaluated in conjunction with equipment, process parameters, and customer verification results. II. 99.995% High Purity and Impurity ControlIn electronic specialty gas applications, gas purity and impurity control are crucial factors affecting process stability. According to Jiayuan Chemical, its hexafluorobutadiene products achieve a purity of 99.995%. For semiconductor and high-end materials customers, clearly defining purity indicators and continuously monitoring batch consistency facilitates incoming material evaluation, process verification, and supplier quality management. III. Focus on Performance and Environmental ManagementAccording to relevant technical documents from the U.S. Environmental Protection Agency, hexafluorobutadiene can be used in etching applications involving specific oxides and materials with low dielectric constants. Its environmental performance should be assessed in conjunction with specific research scope, life cycle, and actual emission controls, and should not be compared absolutically based on a single indicator. Production, transportation, and use must still comply with relevant special gas safety regulations and emission management requirements. ConclusionHigh-purity hexafluorobutadiene is one of the electronic specialty gases worth noting in the field of advanced semiconductor etching. Jiayuan Chemical can provide hexafluorobutadiene products with a purity of up to 99.995%. We welcome relevant customers to further discuss product specifications, packaging, and application requirements. FAQ1. What is the molecular formula of hexafluorobutadiene?Hexafluorobutadiene has the molecular formula C₄F₆ and its English name is Hexafluoro-1,3-butadiene. It is often used in semiconductor-specific dielectric etching processes.2. What is the purity of high-purity hexafluorobutadiene?According to the product information provided by Jiayuan Chemical, the product purity can reach 99.995%; specific indicators and testing items should be based on the latest product specifications and batch inspection documents.3. In which fields is hexafluorobutadiene mainly used?Its main applications include specific dielectric etching processes in semiconductor manufacturing. Its practical applicability needs to be verified based on the thin film material, equipment conditions, and process objectives.
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2026-10-21
A delegation from Changzhou Jiayuan Chemical visited the National Chip Exhibition at the Shanghai International Industry Fair, focusing on the integration of the semiconductor materials industry chain
From October 12th to 16th, 2026, a delegation from Changzhou Jiayuan Chemical Co., Ltd. visited the 26th China International Industry Fair (Shanghai) at the National Exhibition and Convention Center (Shanghai), where the integrated circuit exhibition (CIIC) was held for the first time as an independent event. The delegation focused on examining exhibitors in the semiconductor materials and fluorochemical industry chain, and explored customer development and industry connections in line with the company's new materials business. This year's CIIC brought together over 300 companies from the entire integrated circuit industry chain, covering design, manufacturing, packaging and testing, equipment, and materials, providing a centralized platform for chemical new materials companies to connect with the semiconductor supply chain. Industrial Collaboration: From Fluorochemical Raw Materials to Wafer Manufacturing ApplicationsThe Jiayuan delegation focused on visiting the exhibition areas related to electronic manufacturing and semiconductor materials. Within these areas, companies from the entire industry chain were showcased, ranging from upstream fluorochemical raw materials and ultra-clean, high-purity wet electronic chemicals to downstream fluoroplastic processing products and wafer manufacturing applications. Delegation members exchanged views with several exhibitors on application scenarios and supply collaborations for products such as hydrofluoric acid, ammonium fluoride, PTFE, and PFA. According to the discussions, semiconductor manufacturing has stringent requirements for the purity and batch stability of wet electronic chemicals. The demand for fluoromaterials in equipment sealing, cleaning tanks, and thermal insulation sleeves continues to grow, and collaborative development between material companies and manufacturers is becoming an important direction for industry chain cooperation. Benchmark against product catalogs and advance potential customer development. Prior to the visit, Jiayuan Chemical compiled a list of target companies based on its product catalog, covering wafer foundry, fluorochemicals, electronic bulk gases, and fluoroplastics processing. During the exhibition, the delegation visited relevant booths, focusing on understanding customers' specifications for ultra-clean, high-purity chemicals such as UP-grade hydrofluoric acid, ammonium fluoride, ammonia, sulfuric acid, and hydrogen peroxide, as well as procurement and cooperation models for fluorine materials such as PTFE, FEP, and PFA. Several exhibitors expressed interest in connecting with the delegation, which simultaneously established contact channels, accumulating resources for subsequent sample delivery, technical exchanges, and business negotiations. Taking the exhibition as an opportunity, we will explore practical cooperation in the field of materials.Members of the Jiayuan delegation stated that the National Chip Exhibition at this year's China International Industry Fair (CIIF) showcased the collaborative landscape of the semiconductor material localization process and provided a clear path for chemical new materials companies to enter the semiconductor supply chain. Jiayuan Chemical will take this visit as an opportunity to continuously track the dynamics of the semiconductor functional chemicals and fluorine materials industries, exploring new and pragmatic cooperation paths in areas such as electronic chemical supply chain collaboration and the expansion of downstream applications of fluorine materials, driving high-quality development of the company through technological innovation.
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2026-10-19
99% Ammonium Bifluoride : Dual Advantages in Purity and Impurity Control
In the ammonium bifluoride market, purity is the most direct criterion for customers when selecting products. Our company offers high-grade ammonium bifluoride with a purity of ≥99%, and industrial-grade products with a purity of ≥98%, covering different application needs. The 99% purity specification is the focus of this article. What does 99% mean? Numerically, it's only one percentage point higher than 98%. However, in actual production processes, this one percentage point increase is accompanied by a comprehensive reduction in the impurity system. First, let's look at the control of anions and moisture. Our company's 99% specification products have a drying loss of ≤0.5%, ensuring that the products are not prone to moisture absorption and clumping during storage and transportation, and that the feed flowability is stable; the ignition residue is ≤0.05%, keeping the total amount of inorganic impurities at an extremely low level; chloride is ≤0.005% and sulfate is ≤0.005%, with both indicators tightened simultaneously, effectively reducing the risk of side reactions in downstream reactions and reducing the hidden dangers of equipment corrosion. Metal ion control is the core advantage of the 99% specification. Iron content ≤0.005% means that for glass etching customers, the etched surface is less prone to yellowing, ensuring better light transmittance and appearance quality; for metal surface treatment customers, it means that coating adhesion is not affected by residual iron ions. Heavy metals ≤0.003% leaves room for application in fields highly sensitive to heavy metals, such as electronic chemicals and pharmaceutical intermediates. Another key indicator deserves separate mention: fluorosilicate ≤ 0.2%. Fluorosilicate is one of the most difficult impurities to separate during ammonium bifluoride production, and its content directly affects etching uniformity. In glass frosting processes, high fluorosilicate levels can lead to uneven surface haze; in metal processing, it may interfere with reaction consistency. Our company has consistently controlled this indicator below 0.2%, reflecting the maturity of our refining and purification processes. The industrial-grade 98% purity specification also features a white crystalline appearance and is suitable for common applications such as glass etching, metal surface treatment, and oil extraction acidizing, meeting the needs of industrial customers who require batch stability. 98% is the standard configuration for industrial-grade products, while the 99% purity specification implements stricter limits for impurity control, forming a clear selection gradient. Purity figures are merely the entry point; the impurity ledger is the real substance. The value of our 99% ammonium bifluoride lies in a complete set of quantifiable and verifiable limits for drying loss, ignition residue, chlorides, sulfates, fluorosilicates, iron, and heavy metals, allowing customers to make precise choices based on the actual needs of their processes. FAQQ1: What is the main difference between 99% ammonium bifluoride and 98% industrial grade products?A: The 99% specification adheres to stricter limits for impurity control, including drying loss ≤0.5%, chloride ≤0.005%, sulfate ≤0.005%, fluorosilicate ≤0.2%, iron ≤0.005%, and heavy metals ≤0.003%. The 98% industrial grade is suitable for general industrial applications, while the 99% specification is geared towards applications with higher sensitivity to impurities, forming a clear selection gradient. Q2: What is the practical significance for customers if the fluorosilicate content of 99% specification is controlled below 0.2%?A: Fluorosilicates are among the most difficult impurities to separate during production, and their content directly affects etching uniformity. In glass frosting processes, excessively high levels can lead to uneven surface haze; in metal processing, they may interfere with reaction consistency. Maintaining fluorosilicate levels stably below 0.2% effectively ensures the stability of downstream customer processes across batches. Q3: What do iron and heavy metal indicators mean for glass etching and metal surface treatment customers?A: Iron content ≤0.005% prevents yellow spots on the etched glass surface, ensuring light transmittance and appearance quality; heavy metals ≤0.003% ensures that the adhesion of coatings during metal surface treatment is not affected. These two indicators are crucial for 99% of the specifications to be compatible with high-end industrial scenarios. Q4: How can customers determine whether to choose the 99% or 98% specification?A: The key factor is the process's tolerance for impurities. For routine glass etching, oil extraction acidizing, and ceramic manufacturing, 98% industrial grade is sufficient. If there are specific requirements for etching uniformity, color consistency, or heavy metal residue, we recommend choosing the 99% specification. Customers can request complete testing data for both product grades to make an accurate selection based on their actual process parameters.
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2026-10-16