I believe you have seen and heard many PVDF and lithium hexafluorophosphate projects in recent years. Some are built by fluorine chemical companies, and some are cross-border investments by outside companies. The successive commissioning of these projects has made the supply and demand relationship of PVDF and lithium hexafluorophosphate rapid. Changes have occurred, and its market prices have also fluctuated sharply, and the industry sentiment is very pessimistic.
However, there are a wide variety of fluorine chemical products. In addition to fluorine-containing lithium battery materials, many other products also have excellent application prospects, including hexafluorobutadiene, chlorine trifluoride, carbonyl fluoride, and fluorine-containing polyimide. , polychlorotrifluoroethylene, fusible polytetrafluoroethylene, perfluorosulfonic acid resin, hydrofluoroether, perfluoropolyether, ethylene-tetrafluoroethylene copolymer, etc. This article will take you to learn about some of the more promising fluorine Chemical Products.
01 Hexafluorobutadiene
Hexafluorobutadiene, also known as perfluorobutadiene, hexafluoro-1,3-butadiene, or HFBD for short, is a double-bonded, fully fluorinated compound with a molecular formula of C4F6. Hexafluorobutadiene is an important raw material for synthetic resins and fluorine-containing substances. It can also be used as an etching gas in the semiconductor industry, with the advantages of good selectivity and high precision.
In addition, the GWP of hexafluorobutadiene is only 0.004, and its lifetime in the atmosphere is less than 2 days. It has a very small greenhouse effect. It is a green, environmentally friendly and very marketable perfluoride gas. In recent years, hexafluorobutadiene has become one of the most likely candidates to replace traditional fluorine-containing etching gases due to its excellent etching selectivity, high precision, and easy decomposition in the atmosphere.
Hexafluorobutadiene is one of the new generation of fluorine-containing etching gases currently discovered that can meet the development requirements of etching technology and minimize its impact on the environment. It has broad application prospects. However, the current high-purity hexafluorobutadiene market is still occupied by foreign companies such as Showa Denko, Hosei Chemicals, Merck Group, Linde Gas, and Air Liquide. my country's market demand mainly relies on imports.
In recent years, in the face of increasingly strict semiconductor blockades in Western countries and the growing domestic market demand for fluorine-containing special gases, domestic companies have accelerated their deployment of hexafluorobutadiene, and some companies have broken through industrialization barriers, including China Juxin, Sinochem Blue Sky, CSSC Special Gas, Jinshi Fluorine Industry, Nanda Optoelectronics, etc.
02 fusible polytetrafluoroethylene
PFA is a copolymer of tetrafluoroethylene (TFE) and perfluoroalkyl vinyl ether (PAVE). Because its properties are similar to those of polytetrafluoroethylene, and it can be processed using thermoplastic resin processing methods, it is also called fusible. Polytetrafluoroethylene.
1~10% perfluoroalkyl vinyl ether in the PFA molecule significantly improves the flexibility of the polymer chain and reduces the crystallinity, giving PFA good thermoplasticity and overcoming the shortcomings of PTFE being difficult to process. It can be used with general thermoplastics It is processed by the molding process. Its long-term use temperature is the same as PTFE, and its mechanical properties at high temperatures are better than PTFE.
At the same time, PFA has the excellent chemical corrosion resistance of PTFE, excellent heat resistance, low friction coefficient, self-lubricating, flame retardant, waterproof and other properties. It can be made into anti-corrosion coatings, anti-aging coatings, special filter fibers, reaction Kettle linings, pipe linings, optical cable sheaths, aerospace equipment, etc. are widely used in construction, chemical industry, machinery, electrical, aerospace, medical and many other fields.
At present, the main overseas suppliers of PFA are Chemours, Solvay, Daikin, 3M, AGC, etc., with a market share of nearly 90%. There are relatively few companies producing PFA in China, including Dongyue Group, Yonghe Group, Juhua Group, etc.
03 Perfluorosulfonic acid resin
In recent years, benefiting from multiple factors such as policy support, technological progress, cost reduction and market demand, the hydrogen fuel cell market has shown rapid growth both at home and abroad, which will drive rapid growth in demand for related materials.
Proton exchange membrane is one of the core materials of hydrogen fuel cells. The performance of the membrane directly determines the performance and service life of hydrogen fuel cells. According to the fluorine content, proton exchange membranes can be divided into perfluorinated proton exchange membranes such as perfluorosulfonic acid membranes, partially fluorinated proton exchange membranes such as polyvinylidene fluoride radiation graft membranes, and fluorine-free proton exchange membranes such as polybenzimidazole membranes.
At present, perfluorosulfonic acid proton exchange membrane is the only proton exchange membrane that has been successfully commercialized and actually used in the market. The raw materials for preparing perfluorosulfonic acid resin are mainly tetrafluoroethylene, perfluorosulfonyl vinyl ether monomer (PSVE), etc., whether it is the preparation of PSVE, the polymerization of perfluorosulfonic acid resin, or the film formation of perfluorosulfonic acid resin. There are extremely high technical barriers, so there are not many companies with the production capacity of perfluorosulfonic acid resin globally, and the production capacity is mainly concentrated in companies such as Chemours, Solvay, 3M, and Gore of the United States.
My country's research on perfluorosulfonic acid resin started not late. In the 1970s, the Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, carried out research on the synthesis and polymerization of important monomers of perfluorosulfonic acid resin, and even carried out research on polymer membranes. Research on modification has been carried out, but unfortunately, large-scale production has not yet been achieved.
Domestic perfluorosulfonic acid resin manufacturers include Dongyue Group, Shanghai Sanaifu, Juhua Group, Suzhou Kerun, etc. However, except for Dongyue Group, most other companies do not have the capacity to supply perfluorosulfonic acid resin in batches. Therefore, our country The supply capacity of perfluorosulfonic acid resin is insufficient, and market demand relies heavily on imports. In the future, there will be greater room for domestic substitution of perfluorosulfonic acid resin.
04 Ethylene-tetrafluoroethylene copolymer
ETFE is the strongest fluoroplastic so far. While maintaining the good heat resistance, chemical resistance and electrical insulation properties of polytetrafluoroethylene, its radiation resistance and mechanical properties have been greatly improved, and its tensile strength has been greatly improved. It can reach 50MPa, which is nearly twice that of polytetrafluoroethylene. More importantly, its processing performance is greatly improved, especially its outstanding adhesion to the metal surface, which enables the tight lining process of fluoroplastics and steel to be truly realized.
ETFE not only has excellent impact resistance, electrical conductivity, thermal stability and chemical corrosion resistance, but also has high mechanical strength and good processing performance. It is widely used in chemical industry, electronic communications, equipment manufacturing, aerospace and other fields.
For a long time, ETFE has been monopolized by foreign manufacturers such as AGC, Daikin, Chemours, and 3M. Chinese scientists began research and development in the 1970s, but have not made substantial progress. Domestic demand for ETFE resin products is almost 100% dependent on it. Imports, and foreign countries have implemented embargoes on special ETFE resins needed in my country's Military Industry and National Defense and large aircraft fields, causing ETFE resin to become an important bottleneck restricting the application and development of my country's special fields.
At present, domestic manufacturers have achieved zero breakthroughs and are increasing their ETFE production capacity layout. Companies with production capabilities mainly include Dongyue Group, Juhua Co., Ltd., etc.
05 Fluorinated polyimide
Fluorinated polyimide (FPI) refers to a rigid polymer with a highly regular chemical structure containing imide rings in the main chain. It is produced by melt polycondensation or solution polycondensation reaction of fluorinated dianhydride and fluorinated diamine. Polyamic acid (FPAA) is a polymer material obtained by imidization. Compared with traditional PI, FPI inherits the characteristics of traditional PI such as high strength, high temperature resistance, deformation resistance, and bending resistance, and has the characteristics of good transparency, good electrical insulation, and low dielectric constant.
According to the chemical structure, FPI can be divided into diphenyl ether type FPI, benzene type FPI, benzophenone type FPI, and biphenyl type FPI; according to the performance, it can be divided into fluorine-containing polyetherimide (FPEI), fluorine-containing polyamide imide Amine (FPAI), etc.; according to the fluorine-containing group, it can be divided into two types: fully fluorinated PI and partially fluorinated PI.
In recent years, FPI has been applied in high-end fields including flexible OLED displays and electronic device cooling. Market demand continues to rise. However, FPI core technology is still concentrated in countries such as the United States and Japan. About 90% of the world's FPI is produced in Japan. FPI production technology is complex and requires many types of raw materials. Currently, domestic monomer raw materials with lower technical barriers, such as biphenyltetracarboxylic acid di-BPDA and pyromellitic acid dianhydride PMDA, have been produced on a large scale; for more special single , such as hexafluorodianhydride 6FDA, has gradually broken the monopoly of foreign companies. However, few companies have production capabilities for FPI resin. Some companies, including Shandong Zhongrou and Sanaifu, are promoting FPI industrialization.
06 Hydrofluoroether
Hydrofluoroethers are compounds composed of hydrogen, fluorine, oxygen and carbon atoms. They have an ether structure. Their ozone depletion potential (ODP) is zero, their global warming potential coefficient (GWP) is low, and their atmospheric residence time is very short. They are considered ideal CFCs. alternatives. In addition to excellent environmental properties, hydrofluoroethers also have the best thermal and chemical stability, moderate solubility, low toxicity, non-corrosive, non-flammable, non-smoking, good material compatibility, etc., and are easy to store and transportation.
Due to its excellent insulation, chemical inertness, low surface tension, good volatility, and good compatibility with organic solvents, hydrofluoroether has excellent compatibility with component materials used in semiconductor, chip, and liquid crystal manufacturing industries, so it is widely used in electronics. Cleaning agent is the original use of hydrofluoroether, and it is also one of the main applications at present. In addition, hydrofluoroether can also be used in coolant, anti-fingerprint agent diluent, foaming agent and other fields.
At present, domestic companies with hydrofluoroether production capabilities mainly include Dongyue Group, Juhua Co., Ltd., Shandong Huafu, Quanzhou Yuji, Zhejiang Noah, etc.
07 Ethylene-chlorotrifluoroethylene copolymer
ECTFE is a copolymer of ethylene and chlorotrifluoroethylene, which has extraordinary corrosion resistance to most inorganic and organic chemicals and organic solvents. Until now, except for chlorinated molten alkali or hot amines (such as aniline, dimethylamine), no solvent can corrode ECTFE below 120°C.
Compared with other thermoplastics, ECTFE's resistance to chlorine and chlorine derivatives at high temperatures is particularly outstanding. ECTFE has excellent corrosion resistance, extremely low permeability, excellent electrical properties and extremely smooth surface, and can be used safely in temperatures ranging from low to 149°C.
ECTFE not only has outstanding impact resistance, but also is a tough material with considerable mechanical strength. The surface of ECTFE products, similar to glass, prevents the growth of microorganisms, providing obvious hygienic advantages. Due to these excellent properties, ECTFE is widely used in chemical industry, petroleum drainage, washing, sewage treatment systems, chemical distribution systems and chemical cleaning systems of equipment.
It is understood that currently only Solvay is producing ECTFE in the world, and there is basically no large-scale production capacity in China.
08 2,3,3,3-Tetrafluoropropene
R1234yf, also known as HFO-1234yf, the chemical name is 2,3,3,3-tetrafluoropropene, has zero ODP and low GWP, and has good refrigeration effect. It is one of the most popular ODS substitutes and is known as As the fourth generation refrigerant with the most commercial prospects, it is currently mainly used in the field of automotive air conditioning, and the market demand continues to expand.
Prior to this, the refrigerant for automobile air conditioners mainly used R134a. R134a is a third-generation hydrofluorocarbon (HFCs) refrigerant with zero ODP, but has a high GWP and obvious greenhouse effect. As environmental protection requirements increase, it will be gradually phased out. Compared with R134a, R1234yf has lower GWP, similar physical and chemical properties, and the same atmospheric decomposition products. It can be used in the original vehicle air conditioning system. It is the most potential new refrigerant product to replace R134a and has been used in many cars.
European regulations have banned the use of refrigerants with a GWP >150 in new cars produced and sold within the country since 2017. R134a has been banned in European automobiles.
3N High-Purity CTFE for Advanced Fluoropolymer Manufacturing
I. High-purity trifluorochloroethylene, serving the needs of fine polymerizationChlorotrifluoroethylene (CTFE) is an important fluorinated polymer monomer with CAS number 79-38-9 and molecular formula C₂ClF₃. CTFE can be used to produce chlorotrifluoroethylene resins and is used in the synthesis of related plastics, elastomers, and high-performance lubricants.Changzhou Jiayuan Chemical Co., Ltd. provides trifluorochloroethylene products with a purity of up to 3N . For manufacturers of high-performance fluorinated materials, the core value of high-purity monomers lies in providing a clearer raw material quality basis for polymerization reactions, reducing the interference of non-target impurities on process evaluation, and supporting product consistency control. II. Special Applications of High-Purity Raw Materials: Development of High-Performance PCTFE MaterialsPolychlorotrifluoroethylene (PCTFE) has good chemical resistance and gas and water vapor barrier properties, and can be used in high-barrier packaging, sealing components, cryogenic equipment and certain industrial materials.During PCTFE polymerization, the composition of impurities in the monomer can affect the polymerization reaction and the final resin quality. US Patent Document US5124494A discusses the byproducts, low-boiling-point impurities, and preparation of high-purity monomers in the PCTFE production process, illustrating that impurity control is a crucial step in obtaining suitable polymerization feedstocks.Therefore, 3N high-purity CTFE is particularly noteworthy for companies requiring stringent raw material acceptance, stable polymerization processes, and high-performance resin development. For applications such as low-temperature sealing and high-barrier materials, verification must be conducted in conjunction with resin grade, processing method, and end-use standards; the final product performance cannot be directly inferred from monomer purity alone. III. 3N Purity and Key Impurity ManagementA total purity of 3N means that, according to the corresponding purity definition, the total amount of non-target components is approximately 0.01%. However, total purity does not indicate the specific content of each impurity. For demanding polymerization applications, the purchaser should also pay attention to moisture, residual monomers, by-products, stabilizers, and other process-related impurities, and verify the testing methods and batch inspection reports.Jiayuan Chemical's trifluorochloroethylene products can achieve a purity of up to 3N. Customers can further confirm product specifications, critical impurity limits, packaging methods, and supply requirements based on their actual polymerization route and material application. ConclusionFor the development of high-performance PCTFE resins and other fluoropolymers, monomer purity and impurity control are crucial aspects of raw material evaluation. Jiayuan Chemical provides trifluorochloroethylene with a purity of up to 3N. Fluoropolymer manufacturers are welcome to inquire about product specifications, testing documents, and supply solutions. FAQ1. What applications are suitable for 3N high-purity trifluorochloroethylene?It can be primarily evaluated for use in the production of PCTFE and related fluoropolymers, and is particularly suitable for polymerization processes that emphasize raw material quality and impurity management. Specific applicability needs to be verified by the customer. 2. Why is it necessary to control impurities in high-purity trifluorochloroethylene?Different impurities can affect the polymerization reaction or the final resin quality. In addition to total purity, the content of critical impurities should be confirmed according to process requirements.
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2026-10-23
Jiayuan Chemical: High-purity hexafluorobutadiene aids in precision etching
As advanced semiconductor manufacturing demands increasingly sophisticated high aspect ratio structures and precise pattern control, the purity and process compatibility of electronic specialty gases are becoming increasingly important. Hexafluorobutadiene (C₄F₆) is a specialty gas used for etching semiconductor dielectrics. Changzhou Jiayuan Chemical Co., Ltd. can provide high-purity hexafluorobutadiene with a purity of up to 99.995%, offering product options for related process applications. I. High-requirement etching processesResearch published by the National Institute of Standards and Technology (NIST) indicates that hexafluorobutadiene is suitable for critical semiconductor etching processes requiring high selectivity and high aspect ratio. Its application value lies in helping process developers optimize etching conditions for different thin film materials and structures; however, the actual effectiveness still needs to be evaluated in conjunction with equipment, process parameters, and customer verification results. II. 99.995% High Purity and Impurity ControlIn electronic specialty gas applications, gas purity and impurity control are crucial factors affecting process stability. According to Jiayuan Chemical, its hexafluorobutadiene products achieve a purity of 99.995%. For semiconductor and high-end materials customers, clearly defining purity indicators and continuously monitoring batch consistency facilitates incoming material evaluation, process verification, and supplier quality management. III. Focus on Performance and Environmental ManagementAccording to relevant technical documents from the U.S. Environmental Protection Agency, hexafluorobutadiene can be used in etching applications involving specific oxides and materials with low dielectric constants. Its environmental performance should be assessed in conjunction with specific research scope, life cycle, and actual emission controls, and should not be compared absolutically based on a single indicator. Production, transportation, and use must still comply with relevant special gas safety regulations and emission management requirements. ConclusionHigh-purity hexafluorobutadiene is one of the electronic specialty gases worth noting in the field of advanced semiconductor etching. Jiayuan Chemical can provide hexafluorobutadiene products with a purity of up to 99.995%. We welcome relevant customers to further discuss product specifications, packaging, and application requirements. FAQ1. What is the molecular formula of hexafluorobutadiene?Hexafluorobutadiene has the molecular formula C₄F₆ and its English name is Hexafluoro-1,3-butadiene. It is often used in semiconductor-specific dielectric etching processes.2. What is the purity of high-purity hexafluorobutadiene?According to the product information provided by Jiayuan Chemical, the product purity can reach 99.995%; specific indicators and testing items should be based on the latest product specifications and batch inspection documents.3. In which fields is hexafluorobutadiene mainly used?Its main applications include specific dielectric etching processes in semiconductor manufacturing. Its practical applicability needs to be verified based on the thin film material, equipment conditions, and process objectives.
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2026-10-21
A delegation from Changzhou Jiayuan Chemical visited the National Chip Exhibition at the Shanghai International Industry Fair, focusing on the integration of the semiconductor materials industry chain
From October 12th to 16th, 2026, a delegation from Changzhou Jiayuan Chemical Co., Ltd. visited the 26th China International Industry Fair (Shanghai) at the National Exhibition and Convention Center (Shanghai), where the integrated circuit exhibition (CIIC) was held for the first time as an independent event. The delegation focused on examining exhibitors in the semiconductor materials and fluorochemical industry chain, and explored customer development and industry connections in line with the company's new materials business. This year's CIIC brought together over 300 companies from the entire integrated circuit industry chain, covering design, manufacturing, packaging and testing, equipment, and materials, providing a centralized platform for chemical new materials companies to connect with the semiconductor supply chain. Industrial Collaboration: From Fluorochemical Raw Materials to Wafer Manufacturing ApplicationsThe Jiayuan delegation focused on visiting the exhibition areas related to electronic manufacturing and semiconductor materials. Within these areas, companies from the entire industry chain were showcased, ranging from upstream fluorochemical raw materials and ultra-clean, high-purity wet electronic chemicals to downstream fluoroplastic processing products and wafer manufacturing applications. Delegation members exchanged views with several exhibitors on application scenarios and supply collaborations for products such as hydrofluoric acid, ammonium fluoride, PTFE, and PFA. According to the discussions, semiconductor manufacturing has stringent requirements for the purity and batch stability of wet electronic chemicals. The demand for fluoromaterials in equipment sealing, cleaning tanks, and thermal insulation sleeves continues to grow, and collaborative development between material companies and manufacturers is becoming an important direction for industry chain cooperation. Benchmark against product catalogs and advance potential customer development. Prior to the visit, Jiayuan Chemical compiled a list of target companies based on its product catalog, covering wafer foundry, fluorochemicals, electronic bulk gases, and fluoroplastics processing. During the exhibition, the delegation visited relevant booths, focusing on understanding customers' specifications for ultra-clean, high-purity chemicals such as UP-grade hydrofluoric acid, ammonium fluoride, ammonia, sulfuric acid, and hydrogen peroxide, as well as procurement and cooperation models for fluorine materials such as PTFE, FEP, and PFA. Several exhibitors expressed interest in connecting with the delegation, which simultaneously established contact channels, accumulating resources for subsequent sample delivery, technical exchanges, and business negotiations. Taking the exhibition as an opportunity, we will explore practical cooperation in the field of materials.Members of the Jiayuan delegation stated that the National Chip Exhibition at this year's China International Industry Fair (CIIF) showcased the collaborative landscape of the semiconductor material localization process and provided a clear path for chemical new materials companies to enter the semiconductor supply chain. Jiayuan Chemical will take this visit as an opportunity to continuously track the dynamics of the semiconductor functional chemicals and fluorine materials industries, exploring new and pragmatic cooperation paths in areas such as electronic chemical supply chain collaboration and the expansion of downstream applications of fluorine materials, driving high-quality development of the company through technological innovation.
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2026-10-19
99% Ammonium Bifluoride : Dual Advantages in Purity and Impurity Control
In the ammonium bifluoride market, purity is the most direct criterion for customers when selecting products. Our company offers high-grade ammonium bifluoride with a purity of ≥99%, and industrial-grade products with a purity of ≥98%, covering different application needs. The 99% purity specification is the focus of this article. What does 99% mean? Numerically, it's only one percentage point higher than 98%. However, in actual production processes, this one percentage point increase is accompanied by a comprehensive reduction in the impurity system. First, let's look at the control of anions and moisture. Our company's 99% specification products have a drying loss of ≤0.5%, ensuring that the products are not prone to moisture absorption and clumping during storage and transportation, and that the feed flowability is stable; the ignition residue is ≤0.05%, keeping the total amount of inorganic impurities at an extremely low level; chloride is ≤0.005% and sulfate is ≤0.005%, with both indicators tightened simultaneously, effectively reducing the risk of side reactions in downstream reactions and reducing the hidden dangers of equipment corrosion. Metal ion control is the core advantage of the 99% specification. Iron content ≤0.005% means that for glass etching customers, the etched surface is less prone to yellowing, ensuring better light transmittance and appearance quality; for metal surface treatment customers, it means that coating adhesion is not affected by residual iron ions. Heavy metals ≤0.003% leaves room for application in fields highly sensitive to heavy metals, such as electronic chemicals and pharmaceutical intermediates. Another key indicator deserves separate mention: fluorosilicate ≤ 0.2%. Fluorosilicate is one of the most difficult impurities to separate during ammonium bifluoride production, and its content directly affects etching uniformity. In glass frosting processes, high fluorosilicate levels can lead to uneven surface haze; in metal processing, it may interfere with reaction consistency. Our company has consistently controlled this indicator below 0.2%, reflecting the maturity of our refining and purification processes. The industrial-grade 98% purity specification also features a white crystalline appearance and is suitable for common applications such as glass etching, metal surface treatment, and oil extraction acidizing, meeting the needs of industrial customers who require batch stability. 98% is the standard configuration for industrial-grade products, while the 99% purity specification implements stricter limits for impurity control, forming a clear selection gradient. Purity figures are merely the entry point; the impurity ledger is the real substance. The value of our 99% ammonium bifluoride lies in a complete set of quantifiable and verifiable limits for drying loss, ignition residue, chlorides, sulfates, fluorosilicates, iron, and heavy metals, allowing customers to make precise choices based on the actual needs of their processes. FAQQ1: What is the main difference between 99% ammonium bifluoride and 98% industrial grade products?A: The 99% specification adheres to stricter limits for impurity control, including drying loss ≤0.5%, chloride ≤0.005%, sulfate ≤0.005%, fluorosilicate ≤0.2%, iron ≤0.005%, and heavy metals ≤0.003%. The 98% industrial grade is suitable for general industrial applications, while the 99% specification is geared towards applications with higher sensitivity to impurities, forming a clear selection gradient. Q2: What is the practical significance for customers if the fluorosilicate content of 99% specification is controlled below 0.2%?A: Fluorosilicates are among the most difficult impurities to separate during production, and their content directly affects etching uniformity. In glass frosting processes, excessively high levels can lead to uneven surface haze; in metal processing, they may interfere with reaction consistency. Maintaining fluorosilicate levels stably below 0.2% effectively ensures the stability of downstream customer processes across batches. Q3: What do iron and heavy metal indicators mean for glass etching and metal surface treatment customers?A: Iron content ≤0.005% prevents yellow spots on the etched glass surface, ensuring light transmittance and appearance quality; heavy metals ≤0.003% ensures that the adhesion of coatings during metal surface treatment is not affected. These two indicators are crucial for 99% of the specifications to be compatible with high-end industrial scenarios. Q4: How can customers determine whether to choose the 99% or 98% specification?A: The key factor is the process's tolerance for impurities. For routine glass etching, oil extraction acidizing, and ceramic manufacturing, 98% industrial grade is sufficient. If there are specific requirements for etching uniformity, color consistency, or heavy metal residue, we recommend choosing the 99% specification. Customers can request complete testing data for both product grades to make an accurate selection based on their actual process parameters.
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2026-10-16